Enhanced binding affinity, remarkable selectivity, and high capacity of CO 2 by dual functionalization of a rht-type metal-organic framework

Baiyan Li; Zhijuan Zhang; Yi Li; Kexin Yao; Yihan Zhu; Zhiyong Deng; Fen Yang; Xiaojing Zhou; Guanghua Li; Haohan Wu; Nour Nijem; Yves Jean Chabal; Zhiping Lai; Yu Han; Zhan Shi; Shouhua Feng; Jing Li

doi:10.1002/anie.201105966

Enhanced binding affinity, remarkable selectivity, and high capacity of CO 2 by dual functionalization of a rht-type metal-organic framework

Baiyan Li, Zhijuan Zhang, Yi Li, Kexin Yao, Yihan Zhu, Zhiyong Deng, Fen Yang, Xiaojing Zhou, Guanghua Li, Haohan Wu, Nour Nijem, Yves Jean Chabal, Zhiping Lai, Yu Han, Zhan Shi, Shouhua Feng, Jing Li

Research output: Contribution to journal › Article › peer-review

362 Scopus citations

Abstract

Open and friendly: The smallest member of the rht-type metal-organic frameworks (MOFs, see picture) constructed by a hexacarboxylate ligand with a nitrogen-rich imino triazine backbone shows a significantly enhanced gas binding affinity relative to all other isoreticular rht-type MOFs. The high adsorption capacity and remarkable selectivity of CO 2 are attributed to the high density of open metal and Lewis basic sites in the framework. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Original language	English (US)
Pages (from-to)	1412-1415
Number of pages	4
Journal	Angewandte Chemie International Edition
Volume	51
Issue number	6
DOIs	https://doi.org/10.1002/anie.201105966
State	Published - Dec 23 2011

ASJC Scopus subject areas

Chemistry(all)
Catalysis

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CCDC 831219: Experimental Crystal Structure Determination : catena-(bis(mu~12~-2,4,6-tris(3,5-Dicarboxylatophenylamino)-1,3,5-triazine)-hexa-aqua-hexa-copper unknown solvate)
Li, B. (Creator), Zhang, Z. (Creator), Li, Y. (Creator), Yao, K. (Creator), Zhu, Y. (Creator), Deng, Z. (Creator), Yang, F. (Creator), Zhou, X. (Creator), Li, G. (Creator), Wu, H. (Creator), Nijem, N. (Creator), Chabal, Y. J. (Creator), Lai, Z. (Creator), Han, Y. (Creator), Shi, Z. (Creator), Feng, S. (Creator), Li, J. (Creator), Li, B. (Creator), Zhang, Z. (Creator), Li, Y. (Creator), Yang, F. (Creator), Zhou, X. (Creator), Li, G. (Creator), Wu, H. (Creator), Nijem, N. (Creator), Chabal, Y. J. (Creator), Shi, Z. (Creator), Feng, S. (Creator) & Li, J. (Creator), Cambridge Crystallographic Data Centre, Mar 26 2014
DOI: 10.5517/ccwwyj6, http://hdl.handle.net/10754/624651
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Li, B., Zhang, Z., Li, Y., Yao, K., Zhu, Y., Deng, Z., Yang, F., Zhou, X., Li, G., Wu, H., Nijem, N., Chabal, Y. J., Lai, Z., Han, Y., Shi, Z., Feng, S., & Li, J. (2011). Enhanced binding affinity, remarkable selectivity, and high capacity of CO 2 by dual functionalization of a rht-type metal-organic framework. Angewandte Chemie International Edition, 51(6), 1412-1415. https://doi.org/10.1002/anie.201105966

Li, Baiyan ; Zhang, Zhijuan ; Li, Yi ; Yao, Kexin ; Zhu, Yihan ; Deng, Zhiyong ; Yang, Fen ; Zhou, Xiaojing ; Li, Guanghua ; Wu, Haohan ; Nijem, Nour ; Chabal, Yves Jean ; Lai, Zhiping ; Han, Yu ; Shi, Zhan ; Feng, Shouhua ; Li, Jing. / Enhanced binding affinity, remarkable selectivity, and high capacity of CO 2 by dual functionalization of a rht-type metal-organic framework. In: Angewandte Chemie International Edition. 2011 ; Vol. 51, No. 6. pp. 1412-1415.

@article{59c514ee33e446ebb2094d8f2a8e9273,

title = "Enhanced binding affinity, remarkable selectivity, and high capacity of CO 2 by dual functionalization of a rht-type metal-organic framework",

abstract = "Open and friendly: The smallest member of the rht-type metal-organic frameworks (MOFs, see picture) constructed by a hexacarboxylate ligand with a nitrogen-rich imino triazine backbone shows a significantly enhanced gas binding affinity relative to all other isoreticular rht-type MOFs. The high adsorption capacity and remarkable selectivity of CO 2 are attributed to the high density of open metal and Lewis basic sites in the framework. Copyright {\textcopyright} 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.",

author = "Baiyan Li and Zhijuan Zhang and Yi Li and Kexin Yao and Yihan Zhu and Zhiyong Deng and Fen Yang and Xiaojing Zhou and Guanghua Li and Haohan Wu and Nour Nijem and Chabal, {Yves Jean} and Zhiping Lai and Yu Han and Zhan Shi and Shouhua Feng and Jing Li",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: This work was supported by the Foundation of the National Natural Science Foundation of China (grant numbers 20971054 and 90922034) and the Key Project of the Chinese Ministry of Education. The RU and UTD teams would like to acknowledge support from DOE (grant number DE-FG02-08ER46491). We thank Prof. Xianhe Bu and Dr. Ze Chang (Nankai University, China) and Dr. Ruiping Chen (Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences) for part of the gas adsorption measurements.",

year = "2011",

month = dec,

day = "23",

doi = "10.1002/anie.201105966",

language = "English (US)",

volume = "51",

pages = "1412--1415",

journal = "Angewandte Chemie International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "6",

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Li, B, Zhang, Z, Li, Y, Yao, K, Zhu, Y, Deng, Z, Yang, F, Zhou, X, Li, G, Wu, H, Nijem, N, Chabal, YJ, Lai, Z , Han, Y, Shi, Z, Feng, S & Li, J 2011, 'Enhanced binding affinity, remarkable selectivity, and high capacity of CO 2 by dual functionalization of a rht-type metal-organic framework', Angewandte Chemie International Edition, vol. 51, no. 6, pp. 1412-1415. https://doi.org/10.1002/anie.201105966

Enhanced binding affinity, remarkable selectivity, and high capacity of CO 2 by dual functionalization of a rht-type metal-organic framework. / Li, Baiyan; Zhang, Zhijuan; Li, Yi; Yao, Kexin; Zhu, Yihan; Deng, Zhiyong; Yang, Fen; Zhou, Xiaojing; Li, Guanghua; Wu, Haohan; Nijem, Nour; Chabal, Yves Jean; Lai, Zhiping ; Han, Yu; Shi, Zhan; Feng, Shouhua; Li, Jing.

In: Angewandte Chemie International Edition, Vol. 51, No. 6, 23.12.2011, p. 1412-1415.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Enhanced binding affinity, remarkable selectivity, and high capacity of CO 2 by dual functionalization of a rht-type metal-organic framework

AU - Li, Baiyan

AU - Zhang, Zhijuan

AU - Li, Yi

AU - Yao, Kexin

AU - Zhu, Yihan

AU - Deng, Zhiyong

AU - Yang, Fen

AU - Zhou, Xiaojing

AU - Li, Guanghua

AU - Wu, Haohan

AU - Nijem, Nour

AU - Chabal, Yves Jean

AU - Lai, Zhiping

AU - Han, Yu

AU - Shi, Zhan

AU - Feng, Shouhua

AU - Li, Jing

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: This work was supported by the Foundation of the National Natural Science Foundation of China (grant numbers 20971054 and 90922034) and the Key Project of the Chinese Ministry of Education. The RU and UTD teams would like to acknowledge support from DOE (grant number DE-FG02-08ER46491). We thank Prof. Xianhe Bu and Dr. Ze Chang (Nankai University, China) and Dr. Ruiping Chen (Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences) for part of the gas adsorption measurements.

PY - 2011/12/23

Y1 - 2011/12/23

N2 - Open and friendly: The smallest member of the rht-type metal-organic frameworks (MOFs, see picture) constructed by a hexacarboxylate ligand with a nitrogen-rich imino triazine backbone shows a significantly enhanced gas binding affinity relative to all other isoreticular rht-type MOFs. The high adsorption capacity and remarkable selectivity of CO 2 are attributed to the high density of open metal and Lewis basic sites in the framework. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

AB - Open and friendly: The smallest member of the rht-type metal-organic frameworks (MOFs, see picture) constructed by a hexacarboxylate ligand with a nitrogen-rich imino triazine backbone shows a significantly enhanced gas binding affinity relative to all other isoreticular rht-type MOFs. The high adsorption capacity and remarkable selectivity of CO 2 are attributed to the high density of open metal and Lewis basic sites in the framework. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

UR - http://hdl.handle.net/10754/561964

UR - http://doi.wiley.com/10.1002/anie.201105966

UR - http://www.scopus.com/inward/record.url?scp=84863012676&partnerID=8YFLogxK

U2 - 10.1002/anie.201105966

DO - 10.1002/anie.201105966

M3 - Article

VL - 51

SP - 1412

EP - 1415

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

SN - 1433-7851

IS - 6

ER -

Enhanced binding affinity, remarkable selectivity, and high capacity of CO 2 by dual functionalization of a rht-type metal-organic framework

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CCDC 831219: Experimental Crystal Structure Determination : catena-(bis(mu~12~-2,4,6-tris(3,5-Dicarboxylatophenylamino)-1,3,5-triazine)-hexa-aqua-hexa-copper unknown solvate)

Cite this