Abstract
Open and friendly: The smallest member of the rht-type metal-organic frameworks (MOFs, see picture) constructed by a hexacarboxylate ligand with a nitrogen-rich imino triazine backbone shows a significantly enhanced gas binding affinity relative to all other isoreticular rht-type MOFs. The high adsorption capacity and remarkable selectivity of CO 2 are attributed to the high density of open metal and Lewis basic sites in the framework. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Original language | English (US) |
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Pages (from-to) | 1412-1415 |
Number of pages | 4 |
Journal | Angewandte Chemie International Edition |
Volume | 51 |
Issue number | 6 |
DOIs | |
State | Published - Dec 23 2011 |
ASJC Scopus subject areas
- Chemistry(all)
- Catalysis
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Datasets
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CCDC 831219: Experimental Crystal Structure Determination : catena-(bis(mu~12~-2,4,6-tris(3,5-Dicarboxylatophenylamino)-1,3,5-triazine)-hexa-aqua-hexa-copper unknown solvate)
Li, B. (Creator), Zhang, Z. (Creator), Li, Y. (Creator), Yao, K. (Creator), Zhu, Y. (Creator), Deng, Z. (Creator), Yang, F. (Creator), Zhou, X. (Creator), Li, G. (Creator), Wu, H. (Creator), Nijem, N. (Creator), Chabal, Y. J. (Creator), Lai, Z. (Creator), Han, Y. (Creator), Shi, Z. (Creator), Feng, S. (Creator) & Li, J. (Creator), Dryad Digital Repository, 2012
DOI: 10.5517/ccwwyj6, http://hdl.handle.net/10754/624651
Dataset