Enantioselective Addition of Diethylzinc to Aldehydes Catalyzed by Polymer-Supported Chiral Amino Alcohols. Evidence for a Two Zinc Species Mechanism

Shinichi Itsuno, Jean Frechet

Research output: Contribution to journalLetterpeer-review

142 Scopus citations

Abstract

Polymer-bound chiral amino alcohols (in particular, (dialkylamino)isoborneol) are excellent heterogeneous recyclable catalysts in the enantioselective alkylation of aromatic aldehydes with dialkylzinc.

Original languageEnglish (US)
Pages (from-to)4140-4142
Number of pages3
JournalJournal of Organic Chemistry
Volume52
Issue number18
DOIs
StatePublished - Sep 1 1987

ASJC Scopus subject areas

  • Organic Chemistry

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