Electroless reductions on carbon nanotubes: How critical is the diameter of a nanotube

Yong Guo, Karim Fhayli, Song Li, Yang Yang, Afnan Mashat, Niveen M. Khashab

Research output: Contribution to journalArticlepeer-review

8 Scopus citations

Abstract

Detailed experimental and theoretical studies have been performed to investigate the influence of the diameter of multi-walled carboxy-functionalized carbon nanotubes (CFCNTs) on their ability to reduce PdCl4 2- salt to Pd nanoparticles on their surface at room temperature. The obtained results (inductively-coupled plasmaspectrometry and cyclic voltammetry) show that the reduction ability of CFCNTs with 5 nm diameter (CFCNT5) is stronger than that of CFCNTs with 15 nm diameter (CFCNT15). Density Functional Theory (DFT) calculations suggest that a more negative charge distribution exists on CFCNT5, which makes it a better electron donor to PdCl42-. This journal is © The Royal Society of Chemistry.
Original languageEnglish (US)
Pages (from-to)17693
JournalRSC Advances
Volume3
Issue number39
DOIs
StatePublished - 2013

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Chemistry(all)

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