Electrochemical Synthesis of a Microporous Conductive Polymer Based on a Metal-Organic Framework Thin Film

Chunjing Lu, Teng Ben, Shixian Xu, Shilun Qiu

Research output: Contribution to journalArticlepeer-review

92 Scopus citations

Abstract

A new approach to preparing 3D microporous conductive polymer has been demonstrated in the electrochemical synthesis of a porous polyaniline network with the utilization of a MOF thin film supported on a conducting substrate. The prepared porous polyaniline with well-defined uniform micropores of 0.84 nm exhibits a high BET surface area of 986 m2 g−1 and a high electric conductivity of 0.125 S cm−1 when doped with I2, which is superior to existing porous conducting materials of porous MOFs, CMPs, and COFs.
Original languageEnglish (US)
Pages (from-to)6572-6576
Number of pages5
JournalAngewandte Chemie
Volume126
Issue number25
DOIs
StatePublished - May 22 2014
Externally publishedYes

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