Efforts toward rapid construction of the cortistatin A carbocyclic core via enyne-ene metathesis

Corinne Baumgartner, Sandy Ma, Qi Liu, Brian M. Stoltz

Research output: Contribution to journalArticlepeer-review

33 Scopus citations

Abstract

Our efforts toward the construction of the carbocylic core of cortistatin A via an enyne-ene metathesis are disclosed. Interestingly, an attempted S N2 inversion of a secondary mesylate in our five-membered D-ring piece gave a product with retention of stereochemistry. © 2010 The Royal Society of Chemistry.
Original languageEnglish (US)
Pages (from-to)2915
JournalOrganic & Biomolecular Chemistry
Volume8
Issue number13
DOIs
StatePublished - 2010
Externally publishedYes

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