Efficient singlet oxygen generation by triptycene substituted A3B type zinc(II) phthalocyanine photosensitizers

Bandar R. Al-Sohaimi, Mehmet Pişkin, Bader Ghanem, Shaya Y. Al-Raqa, Mahmut Durmuş*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

11 Scopus citations

Abstract

A3B type unsymmetrical 8,11,15,18,22,25-hexadecyl-2,3-(9,10-dioctyl-6,7-dimethoxy-2,3-dioxytriptycene) (11) and 8,11,15,18,22,25-hexadecyl-2,3-(9,10-diundecyl-6,7-dimethoxy-2,3-dioxytriptycene) (12) zinc(II) phthalocyanines were synthesized for the first time. Their photophysical and photochemical properties were investigated as solutions in toluene and obtained values were compared with unsubstituted zinc(II) phthalocyanine for determination of substitution effect. Both newly synthesized phthalocyanines showed high singlet oxygen generation making them good candidates as photosensitizers for photocatalytic reactions.

Original languageEnglish (US)
Pages (from-to)300-304
Number of pages5
JournalTetrahedron Letters
Volume57
Issue number3
DOIs
StatePublished - Jan 20 2016

Keywords

  • Photosensitizer
  • Phthalocyanine
  • Singlet oxygen
  • Triptycene
  • Zinc

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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