Effect of particles on the induction time of calcium carbonate in synthetic SWRO concentrate

Tarek Waly*, Ruben Munoz, Maria D. Kennedy, Geert-Jan Witkamp, Gary Lee Amy, Jan C. Schippers

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

Particles, which are naturally present in seawater, have been reported to affect the formation of CaCO3 crystals. In this study the effect of foreign particles on induction time was explored. Induction time was monitored using a highly sensitive pH meter mounted in an air-tight glass reactor. Experimental work was performed with synthetic seawater prepared using ultra-pure water with a composition equivalent to 50% recovery SWRO concentrate (based on the composition of seawater from the Gulf of Oman). The prepared synthetic solutions were filtered through filters having different pore sizes namely 0.22 μm; 0. μm and 100kD (≈0.03 μm). In addition, glass beads of diameter 20–30 nm were added in volumes of (1; 0.5 and 0.1 ml) to synthetic seawater to yield an increase in glass/water contact area of 123%, 16% and 1% compared to the total reactor glass area in contact with the synthetic water. Different mixing speeds were applied namely 10; 50; 150 and 300 rpm to investigate the effect of mixing on experimental results. Results showed that fi ltering synthetic seawater and applying different mixing speeds had a negligible effect on the experimental induction time results. On the contrary, the addition of glass beads shortened the induction time substantially from 30% to 100% (immediate precipitation), depending on the amount of beads added.

Original languageEnglish (US)
Pages (from-to)103-111
Number of pages9
JournalDesalination and Water Treatment
Volume18
Issue number1-3
DOIs
StatePublished - Jan 1 2010

Keywords

  • Calcium carbonate
  • Filtration
  • Glass beads
  • Induction time
  • Membrane

ASJC Scopus subject areas

  • Water Science and Technology
  • Ocean Engineering
  • Pollution

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