Effect of canopy structures and their steric interactions on CO2 sorption behavior of liquid-like nanoparticle organic hybrid materials

Youngjune Park, Camille Petit, Patrick Han, Ah-Hyung Alissa Park

Research output: Contribution to journalArticlepeer-review

21 Scopus citations

Abstract

Liquid-like NOHMs with different grafting densities of polymeric canopy were synthesized to evaluate their solvating properties as CO2 solvents. The in situ ATR FT-IR study of NOHMs with linear and branched canopies revealed distinct CO2 capture and corresponding swelling behaviors. These observations suggested that the entropic contribution for CO2 sorption in NOHMs can be tuned via the canopy design. © The Royal Society of Chemistry.
Original languageEnglish (US)
Pages (from-to)8723
JournalRSC Advances
Volume4
Issue number17
DOIs
StatePublished - 2014
Externally publishedYes

Fingerprint

Dive into the research topics of 'Effect of canopy structures and their steric interactions on CO2 sorption behavior of liquid-like nanoparticle organic hybrid materials'. Together they form a unique fingerprint.

Cite this