Doppler-free spectroscopy of KLi

V. Bednarska*, A. Ekers, P. Kowalczyk, W. Jastrzȩbski

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

21 Scopus citations

Abstract

The B 1Π-X 1Σ+ band system of the 39K7Li molecule was investigated by Doppler-free polarizationon spectroscopy in a heat-pipe oven. Precise molecular constants for levels v=0-3 in the ground X 1Σ+ state and levels v=0-2 in the excited B 1Π state were determined. The e-parity components in all three vibrational levels of the B state were found to be subject to rotational perturbations, assigned to interaction with the C 1Σ+ state. The deperturbation analysis provided preliminary constants of the perturbing C state and values of the coupling matrix elements.

Original languageEnglish (US)
Pages (from-to)6332-6337
Number of pages6
JournalJournal of Chemical Physics
Volume106
Issue number15
StatePublished - Apr 15 1997
Externally publishedYes

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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