Discovery and introduction of a (3,18)-connected net as an ideal blueprint for the design of metal-organic frameworks

Vincent Guillerm; Lukasz Jan Weselinski; Youssef Belmabkhout; Amy Cairns; Valerio D’Elia; Łukasz Wojtas; Karim Adil; Mohamed Eddaoudi

doi:10.1038/nchem.1982

Discovery and introduction of a (3,18)-connected net as an ideal blueprint for the design of metal-organic frameworks

Vincent Guillerm, Lukasz Jan Weselinski, Youssef Belmabkhout, Amy Cairns, Valerio D’Elia, Łukasz Wojtas, Karim Adil, Mohamed Eddaoudi

Research output: Contribution to journal › Article › peer-review

301 Scopus citations

Abstract

Metal-organic frameworks (MOFs) are a promising class of porous materials because it is possible to mutually control their porous structure, composition and functionality. However, it is still a challenge to predict the network topology of such framework materials prior to their synthesis. Here we use a new rare earth (RE) nonanuclear carboxylate-based cluster as an 18-connected molecular building block to form a gea-MOF (gea-MOF-1) based on a (3,18)-connected net. We then utilized this gea net as a blueprint to design and assemble another MOF (gea-MOF-2). In gea-MOF-2, the 18-connected RE clusters are replaced by metal-organic polyhedra, peripherally functionalized so as to have the same connectivity as the RE clusters. These metal-organic polyhedra act as supermolecular building blocks when they form gea-MOF-2. The discovery of a (3,18)-connected MOF followed by deliberate transposition of its topology to a predesigned second MOF with a different chemical system validates the prospective rational design of MOFs. © 2014 Macmillan Publishers Limited. All rights reserved.

Original language	English (US)
Pages (from-to)	673-680
Number of pages	8
Journal	Nature Chemistry
Volume	6
Issue number	8
DOIs	https://doi.org/10.1038/nchem.1982
State	Published - Jun 29 2014

ASJC Scopus subject areas

Chemical Engineering(all)
Chemistry(all)

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10.1038/nchem.1982

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title = "Discovery and introduction of a (3,18)-connected net as an ideal blueprint for the design of metal-organic frameworks",

abstract = "Metal-organic frameworks (MOFs) are a promising class of porous materials because it is possible to mutually control their porous structure, composition and functionality. However, it is still a challenge to predict the network topology of such framework materials prior to their synthesis. Here we use a new rare earth (RE) nonanuclear carboxylate-based cluster as an 18-connected molecular building block to form a gea-MOF (gea-MOF-1) based on a (3,18)-connected net. We then utilized this gea net as a blueprint to design and assemble another MOF (gea-MOF-2). In gea-MOF-2, the 18-connected RE clusters are replaced by metal-organic polyhedra, peripherally functionalized so as to have the same connectivity as the RE clusters. These metal-organic polyhedra act as supermolecular building blocks when they form gea-MOF-2. The discovery of a (3,18)-connected MOF followed by deliberate transposition of its topology to a predesigned second MOF with a different chemical system validates the prospective rational design of MOFs. {\textcopyright} 2014 Macmillan Publishers Limited. All rights reserved.",

author = "Vincent Guillerm and Weselinski, {Lukasz Jan} and Youssef Belmabkhout and Amy Cairns and Valerio D{\textquoteright}Elia and {\L}ukasz Wojtas and Karim Adil and Mohamed Eddaoudi",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: Research reported in this publication was supported by the King Abdullah University of Science and Technology (KAUST).",

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Discovery and introduction of a (3,18)-connected net as an ideal blueprint for the design of metal-organic frameworks. / Guillerm, Vincent; Weselinski, Lukasz Jan; Belmabkhout, Youssef; Cairns, Amy; D’Elia, Valerio; Wojtas, Łukasz; Adil, Karim; Eddaoudi, Mohamed.

In: Nature Chemistry, Vol. 6, No. 8, 29.06.2014, p. 673-680.

Research output: Contribution to journal › Article › peer-review

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T1 - Discovery and introduction of a (3,18)-connected net as an ideal blueprint for the design of metal-organic frameworks

AU - Guillerm, Vincent

AU - Weselinski, Lukasz Jan

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AU - Cairns, Amy

AU - D’Elia, Valerio

AU - Wojtas, Łukasz

AU - Adil, Karim

AU - Eddaoudi, Mohamed

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: Research reported in this publication was supported by the King Abdullah University of Science and Technology (KAUST).

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N2 - Metal-organic frameworks (MOFs) are a promising class of porous materials because it is possible to mutually control their porous structure, composition and functionality. However, it is still a challenge to predict the network topology of such framework materials prior to their synthesis. Here we use a new rare earth (RE) nonanuclear carboxylate-based cluster as an 18-connected molecular building block to form a gea-MOF (gea-MOF-1) based on a (3,18)-connected net. We then utilized this gea net as a blueprint to design and assemble another MOF (gea-MOF-2). In gea-MOF-2, the 18-connected RE clusters are replaced by metal-organic polyhedra, peripherally functionalized so as to have the same connectivity as the RE clusters. These metal-organic polyhedra act as supermolecular building blocks when they form gea-MOF-2. The discovery of a (3,18)-connected MOF followed by deliberate transposition of its topology to a predesigned second MOF with a different chemical system validates the prospective rational design of MOFs. © 2014 Macmillan Publishers Limited. All rights reserved.

AB - Metal-organic frameworks (MOFs) are a promising class of porous materials because it is possible to mutually control their porous structure, composition and functionality. However, it is still a challenge to predict the network topology of such framework materials prior to their synthesis. Here we use a new rare earth (RE) nonanuclear carboxylate-based cluster as an 18-connected molecular building block to form a gea-MOF (gea-MOF-1) based on a (3,18)-connected net. We then utilized this gea net as a blueprint to design and assemble another MOF (gea-MOF-2). In gea-MOF-2, the 18-connected RE clusters are replaced by metal-organic polyhedra, peripherally functionalized so as to have the same connectivity as the RE clusters. These metal-organic polyhedra act as supermolecular building blocks when they form gea-MOF-2. The discovery of a (3,18)-connected MOF followed by deliberate transposition of its topology to a predesigned second MOF with a different chemical system validates the prospective rational design of MOFs. © 2014 Macmillan Publishers Limited. All rights reserved.

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Discovery and introduction of a (3,18)-connected net as an ideal blueprint for the design of metal-organic frameworks

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CCDC 959634: Experimental Crystal Structure Determination : octakis(mu~3~-Hydroxo)-undecakis(mu~2~-2-fluorobenzoato)-(N,N-dimethylformamide)-nitrato-hexa-aqua-hexa-terbium

CCDC 953496: Experimental Crystal Structure Determination : catena-[bis(Dimethylammonium) hexakis(mu~6~-1,3,5-tris(4-carboxylatophenyl)benzene)-octakis(mu~3~-hydroxo)-tris(mu~2~-hydroxo)-nona-yttrium(iii) unknown solvate]

CCDC 953497: Experimental Crystal Structure Determination : catena-[bis(mu-9-[4-((3,5-bis[(4,4''-dicarboxylato-1,1':3',1''-terphenyl-5'-yl)ethynyl]phenyl)ethynyl)phenyl]-9H-carbazole-3,6-dicarboxylato)-hexa-aqua-hexa-copper(ii) unknown solvate]

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Discovery and introduction of a (3,18)-connected net as an ideal blueprint for the design of metal-organic frameworks

Abstract

ASJC Scopus subject areas

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Datasets

CCDC 959634: Experimental Crystal Structure Determination : octakis(mu~3~-Hydroxo)-undecakis(mu~2~-2-fluorobenzoato)-(N,N-dimethylformamide)-nitrato-hexa-aqua-hexa-terbium

CCDC 953496: Experimental Crystal Structure Determination : catena-[bis(Dimethylammonium) hexakis(mu~6~-1,3,5-tris(4-carboxylatophenyl)benzene)-octakis(mu~3~-hydroxo)-tris(mu~2~-hydroxo)-nona-yttrium(iii) unknown solvate]

CCDC 953497: Experimental Crystal Structure Determination : catena-[bis(mu-9-[4-((3,5-bis[(4,4''-dicarboxylato-1,1':3',1''-terphenyl-5'-yl)ethynyl]phenyl)ethynyl)phenyl]-9H-carbazole-3,6-dicarboxylato)-hexa-aqua-hexa-copper(ii) unknown solvate]

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