Direct Cross-Coupling of Allylic C(sp3 )−H Bonds with Aryl- and Vinylbromides by Combined Nickel and Visible-Light Catalysis

Long Huang, Magnus Rueping

Research output: Contribution to journalArticlepeer-review

42 Scopus citations

Abstract

An efficient protocol for the direct allylic C(sp3)−H bond activation of unactivated tri- and tetrasubstituted alkenes and their functionalization with aryl- and vinylbromides by nickel and visible-light photocatalysis has been developed. The method allows C(sp2)−C(sp3) formation under mild reaction conditions with good functional-group tolerance and excellent regioselectivity.
Original languageEnglish (US)
Pages (from-to)10333-10337
Number of pages5
JournalAngewandte Chemie International Edition
Volume57
Issue number32
DOIs
StatePublished - Jul 16 2018

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