Dimerization of Terminal Aryl Alkynes Catalyzed by Iron(II) Amine-Pyrazolyl Tripodal Complexes with E/Z Selectivity Controlled by tert-Butoxide

Fei Xue, Xiaolu Song, Ting Ting Lin, Kristin Munkerup, Saad Fahad Albawardi, Kuo-Wei Huang, T. S. Andy Hor, Jin Zhao

Research output: Contribution to journalArticlepeer-review

10 Scopus citations

Abstract

The catalytic activity of iron(II) complexes with functionalized amine-pyrazolyl tripodal ligands toward dimerization of terminal alkynes in the presence a base (KOtBu or NaOtBu) has been studied. An unusual E/Z selectivity of the reaction determined by tert-butoxide was observed.
Original languageEnglish (US)
Pages (from-to)5071-5077
Number of pages7
JournalACS Omega
Volume3
Issue number5
DOIs
StatePublished - May 9 2018

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