The title compound, (C6H21N4)[TiF6]F, was synthesized by the reaction of TiO2, tris-(2-amino-ethyl)amine, HF and ethanol at 463 K in a microwave oven. The crystal structure consists of two crystallographically independent [TiF6]2- anions, two fluoride anions and two triply-protonated tris-(2-amino-ethyl)-amine cations. The Ti atoms are coordinated by six F atoms within slightly distorted octa-hedra. The anions and cations are connected by inter-molecular N - H⋯F hydrogen bonds.
|Original language||English (US)|
|Journal||Acta Crystallographica Section E: Structure Reports Online|
|State||Published - 2008|
ASJC Scopus subject areas
- Materials Science(all)
- Condensed Matter Physics