Device annealing effect in organic solar cells with blends of regioregular poly(3-hexylthiophene) and soluble fullerene

Youngkyoo Kim, Stelios A. Choulis, Jenny Nelson, Donal D.C. Bradley, Steffan Cook, James R. Durrant

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Abstract

Here we report enhanced efficiency bulk heterojunction organic solar cells using blend films of regioregular poly(3-hexylthiophene) (P3HT) and 1-(3-methoxycarbonyl)-propyl-1-phenyl-(6,6) C61 (PCBM) that are subjected to a thermal annealing process. Blend films (P3HT:PCBM=1:1 by weight) were prepared using chlorobenzene and 1,2-dichlorobenzene in order to investigate the role of the solvent. Irrespective of the chosen solvent, the optimal device annealing temperature was found to be 140 °C. The highest power conversion efficiency, 3% under air mass 1.5 simulated solar illumination (100 mW cm2), was achieved by device annealing at 140 °C for 15 min using blend films prepared from chlorobenzene (2.3% for 1,2-dichlorobenzene). © 2005 American Institute of Physics.
Original languageEnglish (US)
JournalApplied Physics Letters
Volume86
Issue number6
DOIs
StatePublished - Feb 7 2005
Externally publishedYes

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