Determination of absolute photoionization cross-sections of oxygenated hydrocarbons

Mingfeng Xie, Zhongyue Zhou, Zhandong Wang, Dongna Chen, Fei Qi*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

41 Scopus citations

Abstract

The near-threshold absolute photoionization cross-sections of 12 oxygenated hydrocarbons, including 1-butanol, 2-butanol, iso-butanol, tert-butanol, 1-pentanol, tert-pentanol, iso-pentanol, methyl tert-butyl ether (MTBE), ethyl tert-butyl ether (ETBE), furan, 2-methylfuran, 2,5-dimethylfuran, were measured in the photon energy range from respective ionization thresholds to 11.5. eV. The experiments were performed with photoionization mass spectrometry and tunable synchrotron vacuum ultraviolet (VUV) light. Binary-liquid-mixtures of the investigated sample and benzene were used in the measurements where benzene acts as a calibration standard, due to its well known photoionization cross-section at the photon energies from its ionization energy (9.24. eV) to 11.5. eV. Photodissociative fragments from the molecules were also observed, and their photodissociation cross-sections are also presented.

Original languageEnglish (US)
Pages (from-to)28-33
Number of pages6
JournalInternational Journal of Mass Spectrometry
Volume293
Issue number1-3
DOIs
StatePublished - 2010
Externally publishedYes

Keywords

  • Absolute photoionization cross-section
  • Mass spectrometry
  • Oxygenated hydrocarbon
  • VUV photoionization

ASJC Scopus subject areas

  • Instrumentation
  • Condensed Matter Physics
  • Spectroscopy
  • Physical and Theoretical Chemistry

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