Determination of absolute photoionization cross-sections of alkanes and cyclo-alkanes

Zhongyue Zhou, Lidong Zhang, Mingfeng Xie, Zhandong Wang, Dongna Chen, Fei Qi*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

40 Scopus citations

Abstract

Absolute photoionization and dissociative photoionization cross-sections of eleven n-alkanes (n-pentane, n-hexane, n-heptane, n-nonane, n-decane, n-undecane, n-dodecane, n-tridecane, n-tetradecane, n-pentadecane and n-hexadecane), three cyclo-alkanes (cyclopentane, methylcyclohexane and transdecahydronaphthalene) and iso-octane were measured for photon energies from the ionization thresholds to 11.5eV. The measurements were performed with the binary-liquid-mixture method utilizing the photoionization cross-sections of benzene as a calibration standard. The ionization energies of n-alkanes and cyclo-alkanes were also calculated at the B3P86/6-31G(d,p) level and by the G3B3 method.

Original languageEnglish (US)
Pages (from-to)1335-1342
Number of pages8
JournalRapid Communications in Mass Spectrometry
Volume24
Issue number9
DOIs
StatePublished - May 15 2010
Externally publishedYes

ASJC Scopus subject areas

  • Analytical Chemistry
  • Spectroscopy
  • Organic Chemistry

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