Dehydrogenative Aromatization and Sulfonylation of Pyrrolidines: Orthogonal Reactivity in Photoredox Catalysis

Krishnamoorthy Muralirajan, Rajesh Kancherla, Magnus Rueping

Research output: Contribution to journalArticlepeer-review

34 Scopus citations

Abstract

Oxidative dehydrogenative aromatization and selective sulfonylation reactions of N-heterocycles under visible-light photoredox catalysis were established. The mild reaction conditions make this approach an appealing and versatile strategy to functionalize/oxidize pyrrolidines whereby arylsulfonyl chlorides were identified to be both catalyst regeneration and sulfonylation reagents.
Original languageEnglish (US)
Pages (from-to)14787-14791
Number of pages5
JournalAngewandte Chemie International Edition
Volume57
Issue number45
DOIs
StatePublished - Oct 11 2018

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