Decarboxylative Aminomethylation of Aryl- and Vinylsulfonates through Combined Nickel- and Photoredox-Catalyzed Cross-Coupling

Lulu Fan, Jiaqi Jia, Hong Hou, Quentin Lefebvre, Magnus Rueping

Research output: Contribution to journalArticlepeer-review

68 Scopus citations

Abstract

A mild approach for the decarboxylative aminomethylation of aryl sulfonates by the combination of photoredox and nickel catalysis through C−O bond cleavage is described for the first time. A wide range of aryl triflates as well as aryl mesylates, tosylates and alkenyl triflates afford the corresponding products in good to excellent yields.
Original languageEnglish (US)
Pages (from-to)16437-16440
Number of pages4
JournalChemistry - A European Journal
Volume22
Issue number46
DOIs
StatePublished - Oct 10 2016

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