Decarbonylative Silylation of Esters by Combined Nickel and Copper Catalysis for the Synthesis of Arylsilanes and Heteroarylsilanes

Lin Guo, Adisak Chatupheeraphat, Magnus Rueping

Research output: Contribution to journalArticlepeer-review

90 Scopus citations

Abstract

An efficient nickel/copper-catalyzed decarbonylative silylation reaction of carboxylic acid esters with silylboranes is described. This reaction provides access to structurally diverse silanes with high efficiency and excellent functional-group tolerance starting from readily available esters.
Original languageEnglish (US)
Pages (from-to)11810-11813
Number of pages4
JournalAngewandte Chemie International Edition
Volume55
Issue number39
DOIs
StatePublished - Aug 25 2016

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