Crystal structure of hexakis(dimethyl sulfoxide-κO)manganese(II) tetraiodide

Mohammed Haque, Bambar Davaasuren, Alexander Rothenberger, Tao Wu

Research output: Contribution to journalArticlepeer-review

5 Scopus citations

Abstract

The title salt, [Mn(C2H6OS)6]I4, is made up from discrete [Mn(DMSO)6]2+ (DMSO is dimethyl sulfoxide) units connected through non-classical hydrogen bonds to linear I4 2- tetraiodide anions. The MnII ion in the cation, situated on a position with site symmetry -3., is octahedrally coordinated by O atoms of the DMSO molecule with an Mn - O distance of 2.1808(12)Å. The I4 2- anion contains a neutral I2 molecule weakly coordinated by two iodide ions, forming a linear centrosymmetric tetraiodide anion. The title compound is isotypic with the Co, Ni, Cu, and Zn analogues.
Original languageEnglish (US)
Pages (from-to)1791-1793
Number of pages3
JournalActa Crystallographica Section E Crystallographic Communications
Volume72
Issue number12
DOIs
StatePublished - Nov 15 2016

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