Cross-Coupling of Sodium Sulfinates with Aryl, Heteroaryl and Vinyl Halides by Nickel/photoredox dual catalysis

Huifeng Yue, Chen Zhu, Magnus Rueping

Research output: Contribution to journalArticlepeer-review

94 Scopus citations

Abstract

An efficient photoredox/nickel dual catalyzed sulfonylation reaction of aryl, heteroaryl, and vinyl halides has been achieved for the first time. This newly developed sulfonylation protocol provides a versatile method for the synthesis of diverse aromatic sulfones at room temperature and shows excellent functional group tolerance. The electrophilic coupling partners are not limited to aryl, heteroaryl and vinyl bromides but also less reactive aryl chlorides are suitable substrates for this transformation.
Original languageEnglish (US)
Pages (from-to)1371-1375
Number of pages5
JournalAngewandte Chemie International Edition
Volume57
Issue number5
DOIs
StatePublished - Jan 5 2018

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