Copper(II) camphorates with tunable pore size in metal-organic frameworks

D. N. Dybtsev, Maxim Yutkin, V. P. Fedin*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

12 Scopus citations

Abstract

Three new homochiral metal-organic coordination polymers [Cu 2camph2dabco] · DMF · 2H2O, [Cu2camph2bipy] · 3DMF · 2H2O, and [Cu2camph2bpe] · 4DMF · 2H2O (H2camph is (+)-cam-phoric acid, bipy is 4,4′-bipyridyl, bpe is trans-bis(4-pyridyl)ethylene) were synthesized by heating copper(II) nitrate, (+)-camphoric acid, and N-donor ligands of different length (dabco, bipy, bpe) in DMF and characterized by powder X-ray diffraction, IR spectroscopy, and TGA. The obtained compounds are isostructural with the previously reported porous zinc(II) camphorates.

Original languageEnglish (US)
Pages (from-to)2246-2249
Number of pages4
JournalRussian Chemical Bulletin
Volume58
Issue number11
DOIs
StatePublished - Jan 1 2009

Keywords

  • Chiral structures
  • Coordination polymers
  • Copper(II) complexes
  • Frameworks
  • Powder X-ray diffraction

ASJC Scopus subject areas

  • Chemistry(all)

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