Cooperative effect of silver in copper-catalyzed trifluoromethylation of aryl iodides using Me3SiCF3

Zhiqiang Weng; Richmond Lee; Weiguo Jia; Yaofeng Yuan; Wenfeng Wang; Feng Xue; Kuo-Wei Huang

doi:10.1021/om200204y

Cooperative effect of silver in copper-catalyzed trifluoromethylation of aryl iodides using Me3SiCF3

Zhiqiang Weng, Richmond Lee, Weiguo Jia, Yaofeng Yuan, Wenfeng Wang, Feng Xue, Kuo-Wei Huang

Research output: Contribution to journal › Article › peer-review

128 Scopus citations

Abstract

An effective model of cooperative effect of silver for the coppercatalyzed trifluoromethylation of activated and unactivated aryl iodides to trifluoromethylated arenes using Me3SiCF3 was achieved with a broad substrate scope. © 2011 American Chemical Society.

Original language	English (US)
Pages (from-to)	3229-3232
Number of pages	4
Journal	Organometallics
Volume	30
Issue number	11
DOIs	https://doi.org/10.1021/om200204y
State	Published - Jun 13 2011

ASJC Scopus subject areas

Organic Chemistry
Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/om200204y

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@article{fbfb64496555451492047fed0e22c09d,

title = "Cooperative effect of silver in copper-catalyzed trifluoromethylation of aryl iodides using Me3SiCF3",

abstract = "An effective model of cooperative effect of silver for the coppercatalyzed trifluoromethylation of activated and unactivated aryl iodides to trifluoromethylated arenes using Me3SiCF3 was achieved with a broad substrate scope. {\textcopyright} 2011 American Chemical Society.",

author = "Zhiqiang Weng and Richmond Lee and Weiguo Jia and Yaofeng Yuan and Wenfeng Wang and Feng Xue and Kuo-Wei Huang",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: We acknowledge the financial support from National Natural Science Foundation of China (21072030) and Fuzhou University (022318) to Z.W. and from KAUST to K.-W.H. Assistance with the crystallographic analysis was provided by Dr. L. L. Koh and Ms. G. K. Tan. R.L. received a KAUST Provost Fellowship, for which he is grateful.",

year = "2011",

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day = "13",

doi = "10.1021/om200204y",

language = "English (US)",

volume = "30",

pages = "3229--3232",

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T1 - Cooperative effect of silver in copper-catalyzed trifluoromethylation of aryl iodides using Me3SiCF3

AU - Weng, Zhiqiang

AU - Lee, Richmond

AU - Jia, Weiguo

AU - Yuan, Yaofeng

AU - Wang, Wenfeng

AU - Xue, Feng

AU - Huang, Kuo-Wei

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: We acknowledge the financial support from National Natural Science Foundation of China (21072030) and Fuzhou University (022318) to Z.W. and from KAUST to K.-W.H. Assistance with the crystallographic analysis was provided by Dr. L. L. Koh and Ms. G. K. Tan. R.L. received a KAUST Provost Fellowship, for which he is grateful.

PY - 2011/6/13

Y1 - 2011/6/13

N2 - An effective model of cooperative effect of silver for the coppercatalyzed trifluoromethylation of activated and unactivated aryl iodides to trifluoromethylated arenes using Me3SiCF3 was achieved with a broad substrate scope. © 2011 American Chemical Society.

AB - An effective model of cooperative effect of silver for the coppercatalyzed trifluoromethylation of activated and unactivated aryl iodides to trifluoromethylated arenes using Me3SiCF3 was achieved with a broad substrate scope. © 2011 American Chemical Society.

UR - http://hdl.handle.net/10754/561800

UR - https://pubs.acs.org/doi/abs/10.1021/om200204y

UR - http://www.scopus.com/inward/record.url?scp=79958126800&partnerID=8YFLogxK

U2 - 10.1021/om200204y

DO - 10.1021/om200204y

M3 - Article

VL - 30

SP - 3229

EP - 3232

JO - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 11

ER -

Cooperative effect of silver in copper-catalyzed trifluoromethylation of aryl iodides using Me3SiCF3

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CCDC 808552: Experimental Crystal Structure Determination : (4,7-Diphenyl-1,10-phenanthroline)(trifluoromethyl)-copper tetrahydrofuran solvate

CCDC 808551: Experimental Crystal Structure Determination : (4,7-Diphenyl-1,10-phenanthroline)-trifluoromethyl-silver tetrahydrofuran solvate

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Cooperative effect of silver in copper-catalyzed trifluoromethylation of aryl iodides using Me3SiCF3

Abstract

ASJC Scopus subject areas

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Datasets

CCDC 808552: Experimental Crystal Structure Determination : (4,7-Diphenyl-1,10-phenanthroline)(trifluoromethyl)-copper tetrahydrofuran solvate

CCDC 808551: Experimental Crystal Structure Determination : (4,7-Diphenyl-1,10-phenanthroline)-trifluoromethyl-silver tetrahydrofuran solvate

Cite this