Control of interpenetration of copper-based MOFs on supported surfaces by electrochemical synthesis

Sumit Sachdeva, Alexey Pustovarenko, Ernst J.R. Sudhölter, Freek Kapteijn, Louis C.P.M. De Smet, Jorge Gascon Sabate*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

15 Scopus citations

Abstract

A study of a copper-based metal-organic framework (MOF) synthesized by an electrochemical route is presented. Morphological and adsorption properties of the MOF synthesized as bulk powder and on supported copper surfaces were investigated. Differences in these properties and structural refinement studies indicate that when 4,4′,4′′-s-triazine-2,4,6-triyl-tribenzoic acid (H3TATB) is used as linker interpenetration can be prevented when the structure is grown on a surface.

Original languageEnglish (US)
Pages (from-to)4018-4022
Number of pages5
JournalCrystEngComm
Volume18
Issue number22
DOIs
StatePublished - Jan 1 2016

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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