Co@NH2-MIL-125(Ti): Cobaloxime-derived metal-organic framework-based composite for light-driven H2 production

M. A. Nasalevich, R. Becker, E. V. Ramos-Fernandez, S. Castellanos, S. L. Veber, M. V. Fedin, F. Kapteijn, J. N.H. Reek*, J. I. Van Der Vlugt, J. Gascon

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

263 Scopus citations

Abstract

We present a synthetic strategy for the efficient encapsulation of a derivative of a well-defined cobaloxime proton reduction catalyst within a photoresponsive metal-organic framework (NH2-MIL-125(Ti)). The resulting hybrid system Co@MOF is demonstrated to be a robust heterogeneous composite material. Furthermore, Co@MOF is an efficient and fully recyclable noble metal-free catalyst system for light-driven hydrogen evolution from water under visible light illumination.

Original languageEnglish (US)
Pages (from-to)364-375
Number of pages12
JournalEnergy and Environmental Science
Volume8
Issue number1
DOIs
StatePublished - Jan 1 2015

ASJC Scopus subject areas

  • Environmental Chemistry
  • Renewable Energy, Sustainability and the Environment
  • Nuclear Energy and Engineering
  • Pollution

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