Confirmation of the absolute configuration of (−)-aurantioclavine

Douglas C. Behenna, Shyam Krishnan, Brian M. Stoltz

Research output: Contribution to journalArticlepeer-review

17 Scopus citations

Abstract

We confirm our previous assignment of the absolute configuration of (-)-aurantioclavine as 7R by crystallographically characterizing an advanced 3-bromoindole intermediate reported in our previous synthesis. This analysis also provides additional support for our model of enantioinduction in the palladium(II)-catalyzed oxidative kinetic resolution of secondary alcohols. © 2010 Elsevier Ltd. All rights reserved.
Original languageEnglish (US)
Pages (from-to)2152-2154
Number of pages3
JournalTetrahedron Letters
Volume52
Issue number17
DOIs
StatePublished - Apr 2011
Externally publishedYes

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