Complexes of tris(o-phenanthroline)nickel(II) and copper(II) bromide with dithio-carbamates derived from α-amino acids

Asma I. El-Said; A. S A Zidan; Mahmoud S. El-Meligy; A. A M Aly; Omar F. Mohammed

doi:10.1023/A:1007188516979

Complexes of tris(o-phenanthroline)nickel(II) and copper(II) bromide with dithio-carbamates derived from α-amino acids

Asma I. El-Said, A. S A Zidan, Mahmoud S. El-Meligy, A. A M Aly, Omar F. Mohammed

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

Complexes of 1,10-o-phenanthroline (o-phen)-Ni^II and Cu^II with dithiocarbamates derived from α-amino acids (glycine, phenylalanine, alanine, methionine and tryptophan) were synthesized and characterized by chemical analysis, spectral and thermal studies and by biological screening; the complexes are non-electrolytes. The empirical formula are [Ni(o-phen)₂(aadtc)] and [Cu₂(o-phen)₂(phaladtc)(H₂O)₂Br₂] where, aadtc = glycinyl-, phenylalaninyl-, alaninyl-, methioninyl- and tryptophanyldithiocarbamate and phaladtc = phenylalaninyldithiocarbamate. The structure of these complexes is probably octahedral. Molecular association through hydrogen bonding between the -NH and the carboxylate groups is proposed for the Ni^II complexes. The Cu^II complex is dimeric with the phenylalaninyldithiocarbamate acting as a bridge.

Original language	English (US)
Pages (from-to)	13-19
Number of pages	7
Journal	Transition Metal Chemistry
Volume	26
Issue number	1-2
DOIs	https://doi.org/10.1023/A:1007188516979
State	Published - Feb 2001
Externally published	Yes

ASJC Scopus subject areas

Inorganic Chemistry

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@article{ab4fc5a85cdb4f52b2782be8272ef8c5,

title = "Complexes of tris(o-phenanthroline)nickel(II) and copper(II) bromide with dithio-carbamates derived from α-amino acids",

abstract = "Complexes of 1,10-o-phenanthroline (o-phen)-NiII and CuII with dithiocarbamates derived from α-amino acids (glycine, phenylalanine, alanine, methionine and tryptophan) were synthesized and characterized by chemical analysis, spectral and thermal studies and by biological screening; the complexes are non-electrolytes. The empirical formula are [Ni(o-phen)2(aadtc)] and [Cu2(o-phen)2(phaladtc)(H2O)2Br2] where, aadtc = glycinyl-, phenylalaninyl-, alaninyl-, methioninyl- and tryptophanyldithiocarbamate and phaladtc = phenylalaninyldithiocarbamate. The structure of these complexes is probably octahedral. Molecular association through hydrogen bonding between the -NH and the carboxylate groups is proposed for the NiII complexes. The CuII complex is dimeric with the phenylalaninyldithiocarbamate acting as a bridge.",

author = "El-Said, {Asma I.} and Zidan, {A. S A} and El-Meligy, {Mahmoud S.} and Aly, {A. A M} and Mohammed, {Omar F.}",

year = "2001",

month = feb,

doi = "10.1023/A:1007188516979",

language = "English (US)",

volume = "26",

pages = "13--19",

journal = "Transition Metal Chemistry",

issn = "0340-4285",

publisher = "Springer Netherlands",

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TY - JOUR

T1 - Complexes of tris(o-phenanthroline)nickel(II) and copper(II) bromide with dithio-carbamates derived from α-amino acids

AU - El-Said, Asma I.

AU - Zidan, A. S A

AU - El-Meligy, Mahmoud S.

AU - Aly, A. A M

AU - Mohammed, Omar F.

PY - 2001/2

Y1 - 2001/2

N2 - Complexes of 1,10-o-phenanthroline (o-phen)-NiII and CuII with dithiocarbamates derived from α-amino acids (glycine, phenylalanine, alanine, methionine and tryptophan) were synthesized and characterized by chemical analysis, spectral and thermal studies and by biological screening; the complexes are non-electrolytes. The empirical formula are [Ni(o-phen)2(aadtc)] and [Cu2(o-phen)2(phaladtc)(H2O)2Br2] where, aadtc = glycinyl-, phenylalaninyl-, alaninyl-, methioninyl- and tryptophanyldithiocarbamate and phaladtc = phenylalaninyldithiocarbamate. The structure of these complexes is probably octahedral. Molecular association through hydrogen bonding between the -NH and the carboxylate groups is proposed for the NiII complexes. The CuII complex is dimeric with the phenylalaninyldithiocarbamate acting as a bridge.

AB - Complexes of 1,10-o-phenanthroline (o-phen)-NiII and CuII with dithiocarbamates derived from α-amino acids (glycine, phenylalanine, alanine, methionine and tryptophan) were synthesized and characterized by chemical analysis, spectral and thermal studies and by biological screening; the complexes are non-electrolytes. The empirical formula are [Ni(o-phen)2(aadtc)] and [Cu2(o-phen)2(phaladtc)(H2O)2Br2] where, aadtc = glycinyl-, phenylalaninyl-, alaninyl-, methioninyl- and tryptophanyldithiocarbamate and phaladtc = phenylalaninyldithiocarbamate. The structure of these complexes is probably octahedral. Molecular association through hydrogen bonding between the -NH and the carboxylate groups is proposed for the NiII complexes. The CuII complex is dimeric with the phenylalaninyldithiocarbamate acting as a bridge.

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U2 - 10.1023/A:1007188516979

DO - 10.1023/A:1007188516979

M3 - Article

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VL - 26

SP - 13

EP - 19

JO - Transition Metal Chemistry

JF - Transition Metal Chemistry

SN - 0340-4285

IS - 1-2

ER -

Complexes of tris(o-phenanthroline)nickel(II) and copper(II) bromide with dithio-carbamates derived from α-amino acids

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