CO2 hydrogenation by phosphorus-nitrogen PN3P-pincer iridium hydride complexes: elucidation of the deactivation pathway.

Yupeng Pan, Chao Guan, Huaifeng Li, Priyanka Chakraborty, Chunhui Zhou, Kuo-Wei Huang

Research output: Contribution to journalArticlepeer-review

4 Scopus citations

Abstract

PN3P-Ir pincer hydride complexes were synthesized and characterized as catalysts and key intermediates in the direct hydrogenation of CO2 to formate under mild conditions. The formation of a dearomatized PN3P*-Ir(i)-CO species was identified as a plausible key process accountable for the loss of catalytic activity in the CO2 hydrogenation.
Original languageEnglish (US)
Pages (from-to)12812-12816
Number of pages5
JournalDalton transactions (Cambridge, England : 2003)
Volume48
Issue number34
DOIs
StatePublished - 2019

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