Cleavage of P-S bonds and oxygenation by a trinuclear iron carboxylate: Synthesis and structures of iron clusters containing group 15/16 anions

Tatiana V. Mitkina, Yanhua Lan, Valeriu Mereacre, Weifeng Shi, Annie K. Powell, Alexander Rothenberger*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

7 Scopus citations

Abstract

The first reactions of the trinuclear oxygen-centred iron carboxylate [Fe33-O)(μ2-piv)6(H 2O)3](piv) (piv = tBuCOO-) with the neutral ligand precursor [RP(S)(μ-S)]2 (R = 4-anisyl) are reported.

Original languageEnglish (US)
Pages (from-to)1136-1139
Number of pages4
JournalDalton Transactions
Issue number9
DOIs
StatePublished - Feb 22 2008

ASJC Scopus subject areas

  • Inorganic Chemistry

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