Changes in physicochemical and transport properties of a reverse osmosis membrane exposed to chloraminated seawater

Lauren Valentino, Tennie Renkens, Thomas Maugin, Jean-Philippe Philippe Crouè, Benito J. Mariñas

Research output: Contribution to journalArticlepeer-review

16 Scopus citations

Abstract

This study contributed to improving our understanding of how disinfectants, applied to control biofouling of reverse osmosis (RO) membranes, result in membrane performance degradation. We investigated changes in physicochemical properties and permeation performance of a RO membrane with fully aromatic polyamide (PA) active layer. Membrane samples were exposed to varying concentrations of monochloramine, bromide, and iodide in both synthetic and natural seawater. Elemental analysis of the membrane active layer by Rutherford backscattering spectrometry (RBS) revealed the incorporation of bromine and iodine into the polyamide. The kinetics of polyamide bromination were first order with respect to the concentration of the secondary oxidizing agent Br2 for the conditions investigated. Halogenated membranes were characterized after treatment with a reducing agent and heavy ion probes to reveal the occurrence of irreversible ring halogenation and an increase in carboxylic groups, the latter produced as a result of amide bond cleavage. Finally, permeation experiments revealed increases in both water permeability and salt passage as a result of oxidative damage.
Original languageEnglish (US)
Pages (from-to)2301-2309
Number of pages9
JournalEnvironmental Science & Technology
Volume49
Issue number4
DOIs
StatePublished - Jan 29 2015

ASJC Scopus subject areas

  • Environmental Chemistry
  • Chemistry(all)

Fingerprint

Dive into the research topics of 'Changes in physicochemical and transport properties of a reverse osmosis membrane exposed to chloraminated seawater'. Together they form a unique fingerprint.

Cite this