Catalytic Intermolecular Cross-Couplings of Azides and LUMO-Activated Unsaturated Acyl Azoliums

Wenjun Li, Manjaly John Ajitha, Ming Lang, Kuo-Wei Huang, Jian Wang

Research output: Contribution to journalArticlepeer-review

14 Scopus citations

Abstract

An example for the catalytic synthesis of densely functionalized 1,2,3-triazoles through a LUMO activation mode has been developed. The protocol is enabled by intermolecular cross coupling reactions of azides with in situ-generated alpha,beta-unsaturated acyl azoliums. High yields and broad scope as well as the investigation of reaction mechanism are reported.
Original languageEnglish (US)
Pages (from-to)2139-2144
Number of pages6
JournalACS Catalysis
Volume7
Issue number3
DOIs
StatePublished - Feb 20 2017

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