TY - JOUR
T1 - Catalytic Ester to Stannane Functional Group Interconversion via Decarbonylative Cross-Coupling of Methyl Esters
AU - Yue, Huifeng
AU - Zhu, Chen
AU - Rueping, Magnus
N1 - KAUST Repository Item: Exported on 2020-12-17
Acknowledgements: H.Y. was supported by the China Scholarship Council.
PY - 2018/1/3
Y1 - 2018/1/3
N2 - An unprecedented conversion of methyl esters to stannanes was realized, providing access to a series of arylstannanes via nickel catalysis. Various common esters including ethyl, cyclohexyl, benzyl, and phenyl esters can undergo the newly developed decarbonylative stannylation reaction. The reaction shows broad substrate scope, can differentiate between different types of esters, and if applied in consecutive fashion, allows the transformation of methyl esters into aryl fluorides or biaryls via fluororination or arylation.
AB - An unprecedented conversion of methyl esters to stannanes was realized, providing access to a series of arylstannanes via nickel catalysis. Various common esters including ethyl, cyclohexyl, benzyl, and phenyl esters can undergo the newly developed decarbonylative stannylation reaction. The reaction shows broad substrate scope, can differentiate between different types of esters, and if applied in consecutive fashion, allows the transformation of methyl esters into aryl fluorides or biaryls via fluororination or arylation.
UR - http://hdl.handle.net/10754/626890
UR - http://pubs.acs.org/doi/10.1021/acs.orglett.7b03669
UR - http://www.scopus.com/inward/record.url?scp=85040790404&partnerID=8YFLogxK
U2 - 10.1021/acs.orglett.7b03669
DO - 10.1021/acs.orglett.7b03669
M3 - Article
C2 - 29297229
AN - SCOPUS:85040790404
VL - 20
SP - 385
EP - 388
JO - Organic Letters
JF - Organic Letters
SN - 1523-7060
IS - 2
ER -