Catalytic asymmetric hydrogenation with the cluster Rh6(CO)10[(-)DIOP]3

R. Mutin, W. Abboud, Jean-Marie Maurice Basset*, D. Sinou

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

8 Scopus citations

Abstract

Rh6(CO)10[(-)DIOP]3 has been isolated after ligand exchange between Rh6(CO)16 and DIOP. The molecular cluster is an efficient catalyst for asymmetric reduction of various prochiral olefins; optical yields up to 47% have been achieved; the results are compared with those obtained with mononuclear rhodium (I) complexes.

Original languageEnglish (US)
Pages (from-to)539-541
Number of pages3
JournalPolyhedron
Volume2
Issue number6
DOIs
StatePublished - Jan 1 1983

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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