Carbonization of Covalent Triazine-based Frameworks via Ionic Liquid Induction

Jiangtao Jia, Zhijie Chen, Youssef Belmabkhout, Karim Adil, Prashant Bhatt, Vera Solovyeva, Osama Shekhah, Mohamed Eddaoudi

Research output: Contribution to journalArticlepeer-review

7 Scopus citations

Abstract

A series of porous organic polymers (POPs) were synthesized using tetrahedral 1,3,5,7-tetracyanoadamantane as the main building block. The synthesis of POP frameworks in the presence of different amounts of molten ZnCl2 as an ionic liquid allowed to alter/enhance the specific BET surface areas of the POPs from 760 to 1560 m2 g-1. The mechanism of in situ ionic liquid induced polymerization and carbonization of the POPs was unveiled and confirmed by IR, EA and solid state NMR.
Original languageEnglish (US)
Pages (from-to)15564-15568
Number of pages5
JournalJournal of Materials Chemistry A
Volume6
Issue number32
DOIs
StatePublished - 2018

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