Carbon dioxide selective adsorption within a highly stable mixed-ligand Zeolitic Imidazolate Framework

Lin Huang, Ming Xue, Qingshan Song, Siru Chen, Ying Pan, Shilun Qiu

Research output: Contribution to journalArticlepeer-review

10 Scopus citations

Abstract

A new mixed-ligand Zeolitic Imidazolate Framework Zn4(2-mbIm) 3(bIm)5·4H2O (named JUC-160, 2-mbIm = 2-methylbenzimidazole, bIm = benzimidazole and JUC = Jilin University China) was synthesized with a solvothermal reaction of Zn(NO3) 2·6H2O, bIm and 2-mbIm in DMF solution at 180 °C. Topological analysis indicated that JUC-160 has a zeolite GIS (gismondine) topology. Study of the gas adsorption and thermal and chemical stability of JUC-160 demonstrated its selective adsorption property for carbon dioxide, high thermal stability, and remarkable chemical resistance to boiling alkaline water and organic solvent for up to one week. © 2014 Elsevier B.V.
Original languageEnglish (US)
Pages (from-to)9-12
Number of pages4
JournalInorganic Chemistry Communications
Volume46
DOIs
StatePublished - Aug 2014
Externally publishedYes

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