Bis[tris-(2-ammonio-ethyl)amine] bis-(penta-fluoridooxidomolybdate) difluoride monohydrate

Karim Adil, J. Marrot, M. Leblanc, V. Maisonneuve*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

6 Scopus citations

Abstract

The first fluoridooxidomolybdate of tris-(2-amino-ethyl)amine (tren), bis-[tris-(2-ammonio-ethyl)amine] bis-(penta-fluorido-oxido-molybdate) difluoride monohydrate, (C6H21N4)2[MoOF5]2F2·H2O, was obtained by solvothermal synthesis using microwave heating from the reaction of molybdenum oxide, tris-2-(aminoethyl)amine, aqueous HF and ethanol at 463 K for 1 h. The structure consists of [MoOF5]2- octa-hedra, isolated fluoride ions, water mol-ecules and triprotonated tren cations. Cohesion is ensured by a network of hydrogen bonds.

Original languageEnglish (US)
JournalActa Crystallographica Section E: Structure Reports Online
Volume63
Issue number5
DOIs
StatePublished - Jan 1 2007

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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