Bisacenaphthopyrazinoquinoxaline derivatives: Synthesis, physical properties and applications as semiconductors for n-channel field effect transistors

Chenhua Tong, Jingjing Chang, Junmin Tan, Gaole Dai, Kuo-Wei Huang, Hardysze Chan, Chunyan Chi

Research output: Contribution to journalArticlepeer-review

3 Scopus citations

Abstract

Several bisacenaphthopyrazinoquinoxaline (BAPQ) based derivatives 1-3 were synthesized by condensation between the acenaphthenequinones and 1,2,4,5-tetraaminobenzene tetrahydrochloride. Their optical, electrochemical and self-assembling properties are tuned by different substituents. Among them, compound 3 possesses a homogeneously distributed low-lying LUMO due to the peripheral substitution with four cyano groups. The corresponding n-channel field effect transistors showed a field effect electron mobility of 5 × 10-3 cm2 V-1 s-1. © 2013 The Royal Society of Chemistry.
Original languageEnglish (US)
Pages (from-to)5683
JournalOrganic and Biomolecular Chemistry
Volume11
Issue number34
DOIs
StatePublished - 2013

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry

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