Benzotrithiophene - A planar, electron-rich building block for organic semiconductors

Christian B. Nielsen, Jamie M. Fraser, Bob C. Schroeder, Junping Du, Andrew J.P. White, Weimin Zhang, Iain Mcculloch

Research output: Contribution to journalArticlepeer-review

59 Scopus citations

Abstract

Chemical equations presented. Several functionalized benzo[1,2-b:3,4- b′:5,6-d′′]trithiophenes have been synthesized and characterized. The fully planar and highly electron-rich material shows great promise as the donor constituent in donor-acceptor type copolymers for use in organic electronics. As a proof of concept, a copolymer with the electron acceptor, 2,1,3-benzothiadiazole, has been prepared. Side-chain modifications have been employed to adjust both the electron-rich character of the monomer and the solubility and processability of the polymer.

Original languageEnglish (US)
Pages (from-to)2414-2417
Number of pages4
JournalOrganic Letters
Volume13
Issue number9
DOIs
StatePublished - May 6 2011

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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