Barium-Catalysed Dehydrocoupling of Hydrosilanes and Borinic Acids: A Mechanistic Insight.

Erwann Le Coz; Ziyun Zhang; Thierry Roisnel; Luigi Cavallo; Laura Falivene; Jean-François Carpentier; Yann Sarazin

doi:10.1002/chem.202000478

Barium-Catalysed Dehydrocoupling of Hydrosilanes and Borinic Acids: A Mechanistic Insight.

Erwann Le Coz, Ziyun Zhang, Thierry Roisnel, Luigi Cavallo, Laura Falivene, Jean-François Carpentier, Yann Sarazin

Research output: Contribution to journal › Article › peer-review

Abstract

Invited for the cover of this issue are the groups of Yann Sarazin at the University of Rennes and Laura Falivene at the King Abdullah University of Science and Technology. The image depicts two barium figures working in tandem to mimic the dinuclear nature of the active species in the catalytic cycle described in the manuscript. Read the full text of the article at 10.1002/chem.201904933.

Original language	English (US)
Journal	Chemistry (Weinheim an der Bergstrasse, Germany)
Volume	26
Issue number	16
DOIs	https://doi.org/10.1002/chem.202000478
State	Published - Feb 26 2020

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10.1002/chem.202000478

https://repository.kaust.edu.sa/bitstream/10754/660449/1/Coz_et_al-2019-Chemistry_-_A_European_Journal.pdf

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CCDC 1961755: Experimental Crystal Structure Determination : {bis[bis(trimethylsilyl)methyl]borinato}-{2,4-di-t-butyl-6-[(1,4,7,10-tetraoxa-13-azacyclopentadecan-13-yl)methyl]phenolato}-barium toluene solvate
Zhang, Z. (Creator), Cavallo, L. (Creator), Falivene, L. (Creator), Le Coz, E. (Creator), Roisnel, T. (Creator), Carpentier, J. (Creator) & Sarazin, Y. (Creator), Cambridge Crystallographic Data Centre, Jun 22 2020
DOI: 10.5517/ccdc.csd.cc23vcfs, http://hdl.handle.net/10754/669189
Dataset
CCDC 1961754: Experimental Crystal Structure Determination : bis{bis[bis(trimethylsilyl)methyl]borinato}-barium toluene solvate
Zhang, Z. (Creator), Cavallo, L. (Creator), Falivene, L. (Creator), Le Coz, E. (Creator), Roisnel, T. (Creator), Carpentier, J. (Creator) & Sarazin, Y. (Creator), Cambridge Crystallographic Data Centre, Jun 22 2020
DOI: 10.5517/ccdc.csd.cc23vcdr, http://hdl.handle.net/10754/669190
Dataset

Cite this

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title = "Barium-Catalysed Dehydrocoupling of Hydrosilanes and Borinic Acids: A Mechanistic Insight.",

abstract = "Invited for the cover of this issue are the groups of Yann Sarazin at the University of Rennes and Laura Falivene at the King Abdullah University of Science and Technology. The image depicts two barium figures working in tandem to mimic the dinuclear nature of the active species in the catalytic cycle described in the manuscript. Read the full text of the article at 10.1002/chem.201904933.",

author = "{Le Coz}, Erwann and Ziyun Zhang and Thierry Roisnel and Luigi Cavallo and Laura Falivene and Jean-Fran{\c c}ois Carpentier and Yann Sarazin",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: L.C., L.F. and Z.Z. thank the King Abdullah University of Science and Technology (KAUST) for supporting this work. For computer time, this research used the resources of the KAUST Super-computing Laboratory (KSL) at KAUST. E.L.C. thanks the Univer-sity of Rennes 1 for a PhD grant.",

year = "2020",

month = feb,

day = "26",

doi = "10.1002/chem.202000478",

language = "English (US)",

volume = "26",

journal = "Chemistry - A European Journal",

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T1 - Barium-Catalysed Dehydrocoupling of Hydrosilanes and Borinic Acids: A Mechanistic Insight.

AU - Le Coz, Erwann

AU - Zhang, Ziyun

AU - Roisnel, Thierry

AU - Cavallo, Luigi

AU - Falivene, Laura

AU - Carpentier, Jean-François

AU - Sarazin, Yann

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: L.C., L.F. and Z.Z. thank the King Abdullah University of Science and Technology (KAUST) for supporting this work. For computer time, this research used the resources of the KAUST Super-computing Laboratory (KSL) at KAUST. E.L.C. thanks the Univer-sity of Rennes 1 for a PhD grant.

PY - 2020/2/26

Y1 - 2020/2/26

N2 - Invited for the cover of this issue are the groups of Yann Sarazin at the University of Rennes and Laura Falivene at the King Abdullah University of Science and Technology. The image depicts two barium figures working in tandem to mimic the dinuclear nature of the active species in the catalytic cycle described in the manuscript. Read the full text of the article at 10.1002/chem.201904933.

AB - Invited for the cover of this issue are the groups of Yann Sarazin at the University of Rennes and Laura Falivene at the King Abdullah University of Science and Technology. The image depicts two barium figures working in tandem to mimic the dinuclear nature of the active species in the catalytic cycle described in the manuscript. Read the full text of the article at 10.1002/chem.201904933.

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DO - 10.1002/chem.202000478

M3 - Article

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JF - Chemistry - A European Journal

SN - 0947-6539

IS - 16

ER -

Barium-Catalysed Dehydrocoupling of Hydrosilanes and Borinic Acids: A Mechanistic Insight.

Abstract

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CCDC 1961755: Experimental Crystal Structure Determination : {bis[bis(trimethylsilyl)methyl]borinato}-{2,4-di-t-butyl-6-[(1,4,7,10-tetraoxa-13-azacyclopentadecan-13-yl)methyl]phenolato}-barium toluene solvate

CCDC 1961754: Experimental Crystal Structure Determination : bis{bis[bis(trimethylsilyl)methyl]borinato}-barium toluene solvate

Cite this