Asymmetric oxidative Lewis base catalysis - Unifying iminium and enamine organocatalysis with oxidations

Magnus Rueping*, Henrik Sundén, Lukas Hubener, Erli Sugiono

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

75 Scopus citations

Abstract

Enantioselective oxidative domino reactions of allylic alcohols to functionalized aldehydes have been developed. The one pot domino oxidation-iminium activation represents a convenient strategy for the enantioselective addition of malonates to allylic alcohols and the asymmetric formation of formyl cyclopropanes.

Original languageEnglish (US)
Pages (from-to)2201-2203
Number of pages3
JournalChemical Communications
Volume48
Issue number16
DOIs
StatePublished - Feb 21 2012
Externally publishedYes

ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

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