Asymmetric H-D exchange reactions of fluorinated aromatic ketones

Yujun Zhao, XiaoZhi Lim, Yuanhang Pan, Lili Zong, Wei Feng, Choonhong Tan, Kuo-Wei Huang

Research output: Contribution to journalArticlepeer-review

15 Scopus citations

Abstract

Chiral bicyclic guanidine catalyzes the asymmetric H-D exchange reactions. Up to 30% ee was achieved. DFT calculations were employed to elucidate and explain the origin of the reaction's stereoselectivity. © 2012 The Royal Society of Chemistry.
Original languageEnglish (US)
Pages (from-to)5479
JournalChemical Communications
Volume48
Issue number44
DOIs
StatePublished - 2012

ASJC Scopus subject areas

  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Ceramics and Composites
  • Chemistry(all)
  • Catalysis
  • Electronic, Optical and Magnetic Materials

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