An enhanced surface passivation effect in InGaN/GaN disk-in-nanowire light emitting diodes for mitigating Shockley–Read–Hall recombination

Chao Zhao, Tien Khee Ng, Aditya Prabaswara, Michele Conroy, Shafat Jahangir, Thomas Frost, John O'Connell, Justin D. Holmes, Peter Parbrook, Pallab Bhattacharya, Boon S. Ooi

Research output: Contribution to journalArticlepeer-review

66 Scopus citations

Abstract

We present a detailed study on the effects of dangling bond passivation and the comparison of different sulfides passivation process on the properties of InGaN/GaN quantum-disk (Qdisk)-in-nanowire based light emitting diodes (NW-LEDs). Our results demonstrated the first organic sulfide passivation process for nitride nanowires (NWs). The results from Raman spectroscopy, photoluminescence (PL) measurements, and X-ray photoelectron spectroscopy (XPS) showed octadecylthiol (ODT) effectively passivated the surface states, and altered the surface dynamic charge, thereby recovered the band-edge emission. The effectiveness of the process with passivation duration was also studied. Moreover, we also compared the electro-optical performance of NW-LEDs emitting at green wavelength before and after ODT passivation. We have shown that the Shockley-Read-Hall (SRH) non-radiative recombination of NW-LEDs can be greatly reduced after passivation by ODT, which led to a much faster increasing trend of quantum efficiency, and higher peak efficiency. Our results highlighted the research opportunity in employing this technique for further design and realization of high performance NW-LEDs and NW-lasers.
Original languageEnglish (US)
Pages (from-to)16658-16665
Number of pages8
JournalNanoscale
Volume7
Issue number40
DOIs
StatePublished - 2015

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