An Efficient and General Strategy toward the Synthesis of Polyethylene-Based Cyclic Polymers

Yu Jiang, Zhen Zhang, De Wang, Nikos Hadjichristidis

Research output: Contribution to journalArticlepeer-review

12 Scopus citations

Abstract

A novel strategy toward well-defined polyethylene-based cyclic homo/copolymers is presented. Tris(3-(anthracen-9-ylmethoxy)propyl)borane, prepared by hydroboration of 9-((allyloxy)methyl)anthracene with BH, was used to initiate the polyhomologation of dimethylsulfoxonium methylide to afford well-defined anthracene-teminated linear polyethylene (PE). The azido and alkynyl groups at α and ω positions of the PE chain were introduced via the anthracene/maleimide Diels-Alder (D-A) reaction and esterification, respectively. Subsequent intramolecular
Original languageEnglish (US)
Pages (from-to)3193-3202
Number of pages10
JournalMacromolecules
Volume51
Issue number8
DOIs
StatePublished - Apr 13 2018

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