[Al12P13O52]3-[(CH2)6N4H3]3+: An anionic aluminophosphate molecular sieve with bronsted acidity

W. Yan, J. Yu, R. Xu*, G. Zhu, F. Xiao, Y. Han, K. Sugiyama, O. Terasaki

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

72 Scopus citations

Abstract

The first anionic aluminophosphate molecular sieve [Al12P13O52]3-[(CH2)6N4H3]3+, denoted AlPO-CJB1, which possesses Bronsted acidity upon removing the templates, is reported. The framework is constructed from strict alternation of Alcentered polyhedra (AlO4 and AlO5) and P-centered PO4 tetrahedra by sharing oxygen atoms at vertices, which creates the anionic open-framework in contrast to previous AlPO(4-n) with neutral open-frameworks.

Original languageEnglish (US)
Pages (from-to)2517-2519
Number of pages3
JournalChemistry of Materials
Volume12
Issue number9
DOIs
StatePublished - 2000
Externally publishedYes

ASJC Scopus subject areas

  • Materials Chemistry
  • Materials Science(all)

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