Access to well-defined isolated Fe(ii) centers on silica and their use in oxidation

Charbel Roukoss, Steven Fiddy, Aimery De Mallmann, Nuria Rendón, Jean-Marie Maurice Basset, Emile Kuntz, Christophe Copéret*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

9 Scopus citations

Abstract

Well-defined FeII isolated sites are obtained by reaction of diaryl-N,N′-diazadiene bis(neosilyl) iron (1) with an aerosil silica, SiO2-(700). This system can be used as a precursor for the catalytic oxidation of cyclohexene into cyclohexene oxide, cyclohexenol and cyclohexenone in the presence of H2O2.

Original languageEnglish (US)
Pages (from-to)5546-5548
Number of pages3
JournalDalton Transactions
Issue number47
DOIs
StatePublished - Dec 3 2007

ASJC Scopus subject areas

  • Inorganic Chemistry

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