A surface organometallic approach to the synthesis of rhenium-based catalysts for the metathesis of olefins: CH3ReO3/Nb2O5

R. Buffon*, A. Auroux, F. Lefebvre, M. Leconte, A. Choplin, Jean-Marie Maurice Basset, W. A. Herrmann

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

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Abstract

The reaction of methyltrioxorhenium with the surface of niobium oxide leads to an active catalyst for the metathesis of acyclic olefins. The activity is related to the niobia surface acidity and to a methylrhenium surface species that resonates at 25 ppm on the 13C MAS NMR spectrum.

Original languageEnglish (US)
Pages (from-to)287-295
Number of pages9
JournalJournal of molecular catalysis
Volume76
Issue number1-3
DOIs
StatePublished - Oct 15 1992

ASJC Scopus subject areas

  • Engineering(all)

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