A lutetium cyclopentadienyl-phosphazene constrained geometry complex (CGC): First isolobal analogues of group 4 cyclopentadienyl-silylamido CGC systems

Konstantin A. Rufanov*, Alex R. Petrov, Vasili V. Kotov, Frederic Laquai, Jörg Sundermeyer

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

28 Scopus citations

Abstract

C5Me4HPMe2 reacts with 1-adamantyl azide to form the first example of a new family of cyclopentadienylideneaminophosphorane ligands (1). Metallation of 1 with Lu(CH2SiMe3)3-(THF)2 leads to the first cyclopentadienyl-phosphazene CGC 2, isolobal to known group 4 cyclopentadienyl-silylamido CGC systems.

Original languageEnglish (US)
Pages (from-to)3805-3807
Number of pages3
JournalEuropean Journal of Inorganic Chemistry
Issue number19
DOIs
StatePublished - Oct 7 2005

Keywords

  • Bridging ligands
  • Constrained geometry complexes
  • Isolobal relationship
  • Lutetium
  • Phosphazenes

ASJC Scopus subject areas

  • Inorganic Chemistry

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