C5Me4HPMe2 reacts with 1-adamantyl azide to form the first example of a new family of cyclopentadienylideneaminophosphorane ligands (1). Metallation of 1 with Lu(CH2SiMe3)3-(THF)2 leads to the first cyclopentadienyl-phosphazene CGC 2, isolobal to known group 4 cyclopentadienyl-silylamido CGC systems.
- Bridging ligands
- Constrained geometry complexes
- Isolobal relationship
ASJC Scopus subject areas
- Inorganic Chemistry