A facile method for the preparation of Covalent Triazine Framework coated monoliths as catalyst support - applications in C1 catalysis

Anastasiya Bavykina, Alma Itzel Olivos Suarez, Dmitrii Osadchii, Rahul Valecha, Robert Franz, Michiel Makkee, Freek Kapteijn, Jorge Gascon

Research output: Contribution to journalArticlepeer-review

23 Scopus citations

Abstract

A quasi Chemical Vapour Deposition method for the manufacturing of well-defined Covalent Triazine Framework (CTF) coatings on cordierite monoliths is reported. The resulting supported porous organic polymer is an excellent support for the immobilisation of two different homogeneous catalysts: 1) an IrIIICp*-based catalyst for the hydrogen production from formic acid, and 2) a PtII-based for the direct activation of methane via Periana chemistry. The immobilised catalysts display a much higher activity in comparison with the unsupported CTF operated in slurry because of improved mass transport. Our results demonstrate that CTF based catalysts can be further optimised by engineering at different length-scales.
Original languageEnglish (US)
Pages (from-to)26060-26065
Number of pages6
JournalACS Applied Materials & Interfaces
Volume9
Issue number31
DOIs
StatePublished - Jul 30 2017

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