A DNA-mimic contact-active functional group for antifouling ultrafiltration membranes

Xinbo Wang, Hong Cheng, Pei-Ying Hong, Xixiang Zhang, Zhiping Lai

Research output: Contribution to journalArticlepeer-review

1 Scopus citations

Abstract

Despite advanced materials and techniques to reduce the fouling issue of membranes, 10–30% of the cost of ultrafiltration (UF) processes have been spent on membrane cleaning. Particularly in water treatment, the traditional heavy metal-based method is challenged due to its environmental pollution risk and increasing public health awareness. Here, we report the synthesis of a metal-free contact-active antifouling and antimicrobial membrane by covalently functionalizing a commercial polyacrylonitril (PAN) UF membrane with 2,4-diamino-1,3,5-triazine (DAT) via a one-step catalyst-free hydrothermal [4 + 2] cyclization of dicyandiamide reaction. The proposed mechanism of the antimicrobial activity of the DAT-functionalized membrane is through strong attraction between the DAT groups and the microbial membrane protein via strong hydrogen bonding, leading to microbial membrane disruption and thus microbe death. A high water flux and good reusability of the membrane against protein in a UF experiment were achieved. The low cost, easy availability of the compounds, as well as the facile reaction offer a high potential of the membrane for real applications in ultrafiltration.
Original languageEnglish (US)
Pages (from-to)669-676
Number of pages8
JournalChemosphere
Volume216
DOIs
StatePublished - Oct 27 2018

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