2D and 3D silver(I)-ethylenediamine coordination polymers with Ag-Ag argentophilic interactions

Ji Xiang Dai, Hai Liang Zhu, Alexander Rothenberger, Qian Feng Zhang*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

9 Scopus citations

Abstract

Two complexes of silver(I) salts with ethylenediamine (etda) as a ligand were prepared and characterized. The study of the crystal structures (of the 2-hydroxy-4-nitro-benzoate trihydrate (1) and nitrate (2)) has shown that the formation of 2D and 3D coordination polymer networks results from etda ligands bridging the silver atoms which are connected via Ag-Ag argentophilic interactions.

Original languageEnglish (US)
Pages (from-to)1112-1116
Number of pages5
JournalZeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Volume62
Issue number9
DOIs
StatePublished - Sep 2007

Keywords

  • Ag-ag interaction
  • Coordination polymer
  • Crystal structure
  • Ethylenediamine
  • Silver compound

ASJC Scopus subject areas

  • Chemistry(all)

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